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Beilstein J. Org. Chem. 2017, 13, 2408–2415, doi:10.3762/bjoc.13.238
Graphical Abstract
Scheme 1: The structures of clethramycin, mediomycins and related linear polyenes.
Scheme 2: The biosynthetic gene clusters for mediomycin (med) from Streptomyces mediocidicus and clethramycin...
Figure 1: HPLC–UV–MS analysis of polyenes. A) LC–UV (360 nm) trace of mycelium methanol extract from DSM4137 ...
Figure 2: HPLC–UV–MS analysis of polyenes from DSM4137 wild type and mutants. A) LC–UV (360 nm) trace of myce...
Scheme 3: The parallel pathways for the biosynthesis of mediomycin A.
Figure 3: HPLC–UV–MS analysis of in vitro assays with amidinohydrolase Medi4948 and sulfotransferase Slf from ...
Beilstein J. Org. Chem. 2016, 12, 2164–2172, doi:10.3762/bjoc.12.206
Figure 1: The structures of marginolactones azalomycin and kanchanamycin, and of the β-lactones ebelactone A ...
Scheme 1: Comparison of the bioinformatic prediction for ebelactone biosynthesis with the known structure of ...
Scheme 2: Proposed model for iteration of module 1 of AzlA1 in azalomycin biosynthesis. The 4-guanidinobutyry...
Figure 2: LC–MS analysis of azalomycin F4a production. a) DSM4137 wild type; b) Δazl (azl disrupted mutant); ...